Implementation of simple and effective fine droplet formation-based spray-assisted liquid phase microextraction for the simultaneous determination of twenty-nine endocrine disruptor compounds and pesticides in rock, soil, water, moss, and feces samples from antarctica using gas chromatography-mass spectrometry

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dc.authorid0000-0003-0745-6863en_US
dc.authorscopusid57215201333en_US
dc.authorwosidDRB-8392-2022en_US
dc.contributor.authorZaman, Buse Tuğba
dc.contributor.authorDalgıç Bozyiğit, Gamze
dc.contributor.authorŞaylan, Meltem
dc.contributor.authorKoçoğlu, Elif Seda
dc.contributor.authorKartoğlu, Bedrihan
dc.contributor.authorAydın, Efe Sinan
dc.contributor.authorGirgin, Ayça
dc.contributor.authorBorahan, Tülay
dc.contributor.authorOflu, Sude
dc.contributor.authorKılınç, Yağmur
dc.contributor.authorBakırdere, Emine Gülhan
dc.contributor.authorBakırdere, Sezgin
dc.date.accessioned2024-01-15T06:19:50Z
dc.date.available2024-01-15T06:19:50Z
dc.date.issued2024en_US
dc.departmentFakülteler, Eczacılık Fakültesi, Eczacılık Meslek Bilimleri Bölümü, Analitik Kimya Ana Bilim Dalıen_US
dc.description.abstractThis study established the simultaneous determination of the selected endocrine-disrupting compounds (EDCs) and pesticides in rock, soil, water, moss, and feces samples collected from the Antarctic region. The spray-assisted droplet formation-based liquid phase microextraction (SADF-LPME) coupled to GC–MS system was developed and validated for the screening and monitoring of 29 selected EDCs and pesticides. Binary solvent system, 1:1 (v/v) dichlormethane: 1,2-dichloroethane mixture was employed as an extraction solvent and sprayed onto sample or standard solutions using a straightforward and practical spray apparatus. The factors afecting the extraction process such as extraction solvent type and ratio, extraction solvent volume (spray repetition), vortexing period, and sample pH were properly optimized. Analytical fgures of the merit of the method were recorded under the optimal extraction/chromatographic conditions. The LOD, LOQ, and enhancement factor were in the range of 1.0 to 6.6 ng/g, 3.2 to 22.1 ng/g, and 3.7 to 158.9, respectively. The method demonstrated a good linear working range for all the selected analytes with proper coefcients of determination. The usability and reliability of the microextraction strategy was confrmed using seawater, moss, and soil samples, and the %recoveries were within an acceptable range (>70%) for all examined samples. The environmental samples collected from the Horseshoe and Faure Islands of the Antarctica region were analyzed to assess the potential pollution of EDCs and pesticides. This method has the potential to be employed for the analysis of EDCs in routine analytical laboratories and for controlling and screening the organic pollutant content of diferent environmental samples.en_US
dc.description.sponsorshipScientifc and Technological Research Council of Türkiye (TÜBİTAK)en_US
dc.identifier.citationZaman, B. T., Bozyiğit, G. D., Şaylan, M., Koçoğlu, E. S., Kartoğlu, B., Aydın, E. S., Girgin, A., Borahan, T., Oflu, S., Kılınç, Y., Bakırdere, E. G., & Bakırdere, S. (2024). Implementation of simple and effective fine droplet formation-based spray-assisted liquid phase microextraction for the simultaneous determination of twenty-nine endocrine disruptor compounds and pesticides in rock, soil, water, moss, and feces samples from antarctica using gas chromatography-mass spectrometry. Environmental Science and Pollution Research, 31(7). 10920-10933 https://doi.org/10.1007/s11356-023-31750-8en_US
dc.identifier.doi10.1007/s11356-023-31750-8en_US
dc.identifier.endpage10933en_US
dc.identifier.issn1614-7499
dc.identifier.issue7en_US
dc.identifier.pmidPMID: 38216815en_US
dc.identifier.scopus2-s2.0-85184519822en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage10920en_US
dc.identifier.urihttps://doi.org/10.1007/s11356-023-31750-8
dc.identifier.urihttps://hdl.handle.net/20.500.13055/627
dc.identifier.volume31en_US
dc.identifier.wosWOS:001142180000011en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.indekslendigikaynak.otherSCI-E - Science Citation Index Expandeden_US
dc.institutionauthorŞaylan, Meltem
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofEnvironmental Science and Pollution Researchen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectAntarctic Regionen_US
dc.subjectEndocrine-Disrupting Compoundsen_US
dc.subjectGas Chromatographyen_US
dc.subjectMossen_US
dc.subjectSeawateren_US
dc.subjectSoilen_US
dc.titleImplementation of simple and effective fine droplet formation-based spray-assisted liquid phase microextraction for the simultaneous determination of twenty-nine endocrine disruptor compounds and pesticides in rock, soil, water, moss, and feces samples from antarctica using gas chromatography-mass spectrometryen_US
dc.typeArticleen_US
dspace.entity.typePublication

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