Preparation and characterization of an acrylated-coumarin-containing photo-crosslinked thiol-ene network: Investigation of the free-volume, thermal, UV, and photoluminescence properties

Basit Öğe Kaydı
dc.authorid0009-0004-6294-6819
dc.authorid0000-0002-7869-1281
dc.authorid0009-0002-4224-4620
dc.authorid0009-0000-5171-0596
dc.authorid0000-0002-6587-883X
dc.authorid0000-0002-6500-7903
dc.authorid0000-0003-1043-6476
dc.contributor.authorUyumaz, Fatmanur
dc.contributor.authorArtuç, Gamze Özgül
dc.contributor.authorPehlivan, Gamze
dc.contributor.authorAkdoğan, Ayça
dc.contributor.authorYahşi, Uğur
dc.contributor.authorTav, Cumali
dc.contributor.authorBulut, Mustafa
dc.contributor.authorKahraman, Memet Vezir
dc.date.accessioned2025-03-04T09:15:28Z
dc.date.available2025-03-04T09:15:28Z
dc.date.issued2025
dc.departmentFakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Mühendisliği Bölümü
dc.description.abstractCoumarin, a versatile compound, has attracted great interest in polymer science due to its unique properties and diverse applications. The use of coumarins in polymer research opens avenues for the development of materials with improved functionalities. In this study, an acrylated coumarin (a-coumarin) compound containing polymeric films was obtained via UV curing through a thiol-ene click reaction with a free radical mechanism. The obtained a-coumarin-containing polymeric films were subjected to functional characterization using FTIR and NMR analyses and thermal characterization via DSC and TGA. UV–vis and PL analyses were performed to determine the optical properties. Using positron anni hilation lifetime spectroscopy (PALS), the free volume and proportional free volume fraction of the films were analyzed both below and above the glass transi tion temperature (Tg). The Tg values obtained from PALS were several degrees lower than those obtained via DSC. A-coumarin additives inhibit segmental mobility, hence reducing the proportional free volume fraction and increasing the Tg. This study is the first in the literature to investigate the free volume properties of coumarin-containing polymeric films. The study reveals the impact of a-coumarin on thermal, optical, and free volume properties, paving the way for the design of advanced functional materials.
dc.identifier.citationUyumaz, F., Artuç, G. Ö., Pehlivan, G., Akdoğan, A., Yahşi, U., Tav, C., Bulut, M., & Kahraman, M. V. (2025). Preparation and characterization of an acrylated-coumarin-containing photo-crosslinked thiol-ene network: Investigation of the free-volume, thermal, UV, and photoluminescence properties. Polymer Engineering and Science, pp. 1-12. https://doi.org/10.1002/pen.27125
dc.identifier.doi10.1002/pen.27125
dc.identifier.endpage12
dc.identifier.issn1548-2634
dc.identifier.issn0032-3888
dc.identifier.scopusqualityQ2
dc.identifier.startpage1
dc.identifier.urihttps://doi.org/10.1002/pen.27125
dc.identifier.urihttps://hdl.handle.net/20.500.13055/928
dc.identifier.wosWOS:001418992200001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynak.otherSCI-E - Science Citation Index Expanded
dc.institutionauthorArtuç, Gamze Özgül
dc.institutionauthorid0000-0002-7869-1281
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofPolymer Engineering and Science
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectAcrylated Coumarin
dc.subjectFree Volume
dc.subjectFree Volume Fraction
dc.subjectPolymeric Film
dc.subjectPositron Annihilationlifetime Spectroscopy
dc.titlePreparation and characterization of an acrylated-coumarin-containing photo-crosslinked thiol-ene network: Investigation of the free-volume, thermal, UV, and photoluminescence properties
dc.typeArticle
dspace.entity.typePublication

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim
İsim:
Tam Metin / Full Text
Boyut:
2.62 MB
Biçim:
Adobe Portable Document Format
İndir
Lisans paketi
Listeleniyor 1 - 1 / 1
Kapalı Erişim
İsim:
license.txt
Boyut:
1.17 KB
Biçim:
Item-specific license agreed upon to submission
Açıklama:
İndir

Koleksiyon

Kimya Mühendisliği Bölümü Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu